Thienothiophene-based organic light-emitting diode: synthesis, photophysical properties and application

• Recep Isci and
• Turan Ozturk

Beilstein J. Org. Chem. 2023, 19, 1849–1857, doi:10.3762/bjoc.19.137

• for organic electronic applications [12][35]. Dimesitylboron (DMB), with its unoccupied p-orbital, is an electron-acceptor organoboron compound used in several donor–acceptor systems to provide the system with pull–push interaction [36][37]. In this work, we have designed and synthesized a D–π–A model

Synthesis, structure, and properties of switchable cross-conjugated 1,4-diaryl-1,3-butadiynes based on 1,8-bis(dimethylamino)naphthalene

• Semyon V. Tsybulin,
• Ekaterina A. Filatova,
• Alexander F. Pozharskii,
• Valery A. Ozeryanskii and
• Anna V. Gulevskaya

Beilstein J. Org. Chem. 2023, 19, 674–686, doi:10.3762/bjoc.19.49

• systems; 1,4-diaryl-1,3-butadiynes; donor–acceptor systems; Glaser–Hay reaction; Introduction π-Conjugated oligomers and polymers attracted considerable attention from the very start as a promising class of semiconductors, chemosensors, and various electronic devices [1][2]. Although silicon and

Tetraphenylethylene-embedded pillar[5]arene-based orthogonal self-assembly for efficient photocatalysis in water

• Zhihang Bai,
• Krishnasamy Velmurugan,
• Xueqi Tian,
• Minzan Zuo,
• Kaiya Wang and
• Xiao-Yu Hu

Beilstein J. Org. Chem. 2022, 18, 429–437, doi:10.3762/bjoc.18.45

• to improve the efficiency of chemical reactions in water [26]. Until now, various macrocyclic host-assisted supramolecular donor–acceptor systems have been developed based on the FRET process and further utilized for different photochemical reactions [27][28]. For instance, Yi et al. [29] developed a

Synthesis and properties of quinazoline-based versatile exciplex-forming compounds

• Rasa Keruckiene,
• Simona Vekteryte,
• Ervinas Urbonas,
• Matas Guzauskas,
• Eigirdas Skuodis,
• Dmytro Volyniuk and
• Juozas V. Grazulevicius

Beilstein J. Org. Chem. 2020, 16, 1142–1153, doi:10.3762/bjoc.16.101

• an electron acceptor in donor–acceptor systems [14]. The target compounds were obtained by nucleophilic substitution reaction of the intermediate quinazoline derivative Q1 with the corresponding donor compounds. The chemical structures were characterized by 1H NMR, 13C NMR, ATRIR spectroscopy and

Bipyrrole boomerangs via Pd-mediated tandem cyclization–oxygenation. Controlling reaction selectivity and electronic properties

• Liliia Moshniaha,
• Marika Żyła-Karwowska,
• Joanna Cybińska,
• Piotr J. Chmielewski,
• Ludovic Favereau and
• Marcin Stępień

Beilstein J. Org. Chem. 2020, 16, 895–903, doi:10.3762/bjoc.16.81

• measurements show that helicene-like boomerangs may be usable as circularly polarized luminescent materials. Keywords: donor–acceptor systems; double C–H bond activation; helicenes; pyrroles; Introduction Nanographenes and other polycyclic aromatics as well as their heterocyclic analogues are typically

• features characteristic of donor–acceptor systems (Supporting Information File 1, Figures S25–S30). For dilactams, cRnO, the HOMO orbital is primarily localized on the dilactam (bipyrrole) moiety, however, with some non-zero amplitudes on the NDA/NMI fragment, whereas the LUMO level encompasses the π

Reversible photoswitching of the DNA-binding properties of styrylquinolizinium derivatives through photochromic [2 + 2] cycloaddition and cycloreversion

• Sarah Kölsch,
• Heiko Ihmels,
• Jochen Mattay,
• Norbert Sewald and
• Brian O. Patrick

Beilstein J. Org. Chem. 2020, 16, 111–124, doi:10.3762/bjoc.16.13

• relative to the ones of the DNA base pairs [75][76]. Considering a dipole moment of the donor–acceptor systems 3a–c along the long molecular axis, a binding mode in which the ligand is accommodated in the intercalation site with its long molecular axis perpendicular to the long axis of the binding site

Emission solvatochromic, solid-state and aggregation-induced emissive α-pyrones and emission-tuneable 1H-pyridines by Michael addition–cyclocondensation sequences

• Natascha Breuer,
• Irina Gruber,
• Christoph Janiak and
• Thomas J. J. Müller

Beilstein J. Org. Chem. 2019, 15, 2684–2703, doi:10.3762/bjoc.15.262

• , dimethylamino-substituted α-pyrones, as donor–acceptor systems, display remarkable photophysical properties, such as strongly red-shifted absorption and emission maxima with daylight fluorescence and fluorescence quantum yields up to 99% in solution and around 11% in the solid state, as well as pronounced

Synthesis and spectroscopic properties of β-meso directly linked porphyrin–corrole hybrid compounds

• Baris Temelli and
• Hilal Kalkan

Beilstein J. Org. Chem. 2018, 14, 187–193, doi:10.3762/bjoc.14.13

• characters, high fluorescence quantum yields and favorable electronic properties. Porphyrin–corrole conjugates have been successfully used as donor–acceptor systems in photoinduced charge separation processes. It was shown that derivatives of these conjugates could be potentially used in photovoltaic

Advances in the synthesis of functionalised pyrrolotetrathiafulvalenes

• Luke J. O’Driscoll,
• Sissel S. Andersen,
• Marta V. Solano,
• Dan Bendixen,
• Morten Jensen,
• Troels Duedal,
• Jess Lycoops,
• Cornelia van der Pol,
• Rebecca E. Sørensen,
• Karina R. Larsen,
• Kenneth Myntman,
• Christian Henriksen,
• Stinne W. Hansen and
• Jan O. Jeppesen

Beilstein J. Org. Chem. 2015, 11, 1112–1122, doi:10.3762/bjoc.11.125

• served as intermediates and model systems in the synthesis of, for example, donor–acceptor systems, chemosensors and materials with molecular electronics applications [44][56]. The N-tosyl protecting group of precursor MPTTFs (4c, 4d, 4f and 4g) must first be removed. This can be achieved in excellent

A hybrid electron donor comprising cyclopentadithiophene and dithiafulvenyl for dye-sensitized solar cells

• Gleb Sorohhov,
• Chenyi Yi,
• Michael Grätzel,
• Silvio Decurtins and
• Shi-Xia Liu

Beilstein J. Org. Chem. 2015, 11, 1052–1059, doi:10.3762/bjoc.11.118

• unit. Keywords: donor–acceptor systems; dye-sensitized solar cells; electrochemistry; intramolecular charge transfer; Knoevenagel reaction; tetrathiafulvalene; Introduction Dye-sensitized solar cells (DSSCs) have been intensively investigated as an alternative to silicon-based solar cells [1][2][3][4

The Ugi four-component reaction as a concise modular synthetic tool for photo-induced electron transfer donor-anthraquinone dyads

• Sarah Bay,
• Gamall Makhloufi,
• Christoph Janiak and
• Thomas J. J. Müller

Beilstein J. Org. Chem. 2014, 10, 1006–1016, doi:10.3762/bjoc.10.100

• dyad 1 an electronic prerequisite for electronically favored electron-transfer processes in donor–acceptor systems is the spatial proximity of PT and AQ. This conformer is additionally stabilized by π-stacking of the donor and the acceptor, which is adopted in the solid state and results in a strong

• concept to donor–acceptor systems is very general, easy to perform and readily expandable to all kinds of functional π-electron systems. The Weller approximation of the Gibbs free energies of the PET allows a semiquantitative evaluation and optimization of photo-induced charge-separation systems. Studies